The
marble and granite resin process: How and why
by
Filippo Emanuel, Tenax USA, Charlotte, NC Posted:
June
4, 2003
Over
the past few years, a number of slab producers have invested in
large-scale operations for applying resin to granite slabs. This
article explains some of the benefits to this process.
Natural
stone comes in many different colors, shapes and textures. A lot of
these materials unfortunately have natural defects, mostly fractures
and superficial holes and pits. In the quarry, the ever-evolving
extraction technology has reduced the number of damaged or
completely destroyed blocks, leaving the major repair burden to the
polishing phase.
Besides the logical tendency to save as many slabs as possible,
there are also other different reasons why the technology evolved
for stone enhancement and repair. The main reasons include the
following:
- Several materials are naturally fractured and could not
otherwise be sold or marketed even if they are superior in terms
of color, durability and other qualities.
- There is a growing tendency in producing thinner slabs to
reduce transportation costs and open up new markets and different
stone uses.
- The waste from manufacturing slabs of particular materials
(especially some marbles) could represent 35 to 40% of production,
thus considerably increasing the cost of the remaining slabs.
- Many different kinds of granites have natural micro-fissures
that compromise the final polished effect, thus reducing the
beauty of the material.
- There are materials just too fragile to be polished, leaving
no solution but to close down quarries.
- Some granites have fissures that pass through the slab and
considerably decrease the strength of the slabs and pose an hazard
when used as outside paneling.
- Limited reserves of a particular color of stone leave only the
worst and more damaged veins to be quarried.
Different
solutions for different materials
In
marble polishing, the use of polyester resin to fill and reinforce
the slabs has been an accepted solution for over 50 years. All the
travertine and a great number of marbles are nowadays filled with
either polyester resin or cement. Those fillers are mainly used for
aesthetic effects and to avoid open holes in the surface of the
material.
The more fragile marbles have also a reinforced backing support,
usually in a form of a fiberglass mesh. This solution gives a strong
and durable surface for transportation purposes and to avoid
breakage. In this process, the main material used with the net is a
polyester resin. Although not a very strong glue, polyester resin in
marble is still the method of choice, mainly to reduce costs (and it
still has sufficient bonding strength due to the relatively soft and
porous substance of the marble).
The polyester resin has also the added value of fast drying time,
making it a perfect solution for automatic line manufacturing.
Nowadays there are many different kinds of polyester resins, with
different viscosity, color and hardening times. Some resins have
even the capability of UV hardening, allowing a very fast curing
time.
Generally, the systems commonly used in marble processing are not
satisfactory for granite processing lines. The main reasons for this
lie in the different chemical structures of the two materials.
Granite is much harder, with microscopic fissures and a different
absorption rate. The very thin cracks represent an additional
problem, since no polyester resin would have the capability to
deeply penetrate in the stone, harden up and give a sufficient
strength to the material.
About 20 years ago, after some unsuccessful trials with polyester
and acrylic products, a new family of products was tested. Using
materials with optimum adhesion (epoxy systems) on granite, the
typical problems were resolved and a new technology was developed.
The epoxy resin has shown the capability to run into each of the
cracks and fill all of the pits and micro-fissures present in the
granite. Additionally, its long hardening time allows the glue to
penetrate deeply into the stone before the complete curing will
occur.
This very durable and extremely elastic family of glues can also
follow the different thermal expansion of the granite, leaving the
treated product capable of sustaining a wide array of temperatures,
making it suitable for inside and outside usage. They also provide a
solution when there is a need to glue the granite slab to another
material (either aluminum honeycomb, glass or steel).
The extremely high strength of the glue helps to fix any
structural defects, giving the slab a very strong and durable
finish.
How
is it applied and how does it work? Before being
treated, the surface of a granite slab has to be honed; to allow the
surface of the material to evenly absorb the resin. The material
also needs to be completely clean and dry, so the resin can deeply
penetrate in the smallest cracks of the surface.
This process requires special convection ovens or two to three
days in favorable dry working conditions. After being mixed in the
right ratio (either using a scale or an automatic mixing dispenser),
the resin is then spread on the whole surface.
Nowadays, there are hundreds of different epoxy systems for
granite, with different physical characteristics. The right system
is always chosen in relation to the color of the granite, the
machinery available and the desired results to be obtained.
After the system is completely cured (usually it takes up to 24
hours, depending on the system and the equipment used) the slab is
ready to be polished.
During the polishing process, the first steps are focused on
removing all excess resin poured on top of the slab, leaving only
the resin that has filled into the cracks or the pits. In this way,
the epoxy resin will not form a film on top of the granite, and it
will be present only in the interspaces and in the micro-fissures.
One of the first noticeable affects of the resin is a darkening
effect on the whole surface of the slab. This is due to the effect
of the resin on the quartz itself. This byproduct enhances the color
of the slab and allows for a better polishing effect as a final
result. On lighter materials, and when this effect is not desired,
the application of special epoxy systems allows the material to
maintain its color.
Common
problems and issues
One
of the first questions that comes with a resin-cured granite slab is
how to match the color between the "darkened" surface of the slab
and the subsequent polished edge of a finished product (like a
kitchen countertop).
There are special products on the market for enhancing the color
of granite and marble. Applying these products will allow you to
permanently match the two colors with one application. Beware,
though, of easy solutions such as mineral oil or a cheap color
enhancer. These products will solve the problem only momentary,
eventually leaving the customers dissatisfied in the long run.
Another issue is the durability of the process. The epoxy resin
was invented in the early 1940s to develop a strong and durable
product in the aeronautical engineering. The historical data
available today refers only to that particular branch of the
industry, while in the stone industry there are only laboratory
tests to support the long-term effect and durability. So far, none
of these tests have proven that the system cannot last for a long
time.
Another question is whether the epoxy resin is safe for kitchen
countertop surfaces, and whether they will be damaged if a homeowner
were to place a hot item on the surface. The answer is that the
resin materials used must comply with the latest FDA rules for food
contact. As far as high temperature goes, the epoxy system has the
tendency to soften up in presence of high temperatures. However,
unless there is a particularly large hole that was repaired with the
epoxy system, the small fractures are not affected by the local
application of heat. Even if there is a large patch of epoxy glue
visible, it will go back to its original status as soon as the
temperature goes back down to a normal level.
Conclusions
Although the epoxy resining of the granite slabs has
been scrutinized by the "purists" in this business, it has grown now
to a point where it is not only accepted by the majority of the
operators, but often required in a lot of materials. The resin has
the double effect of assuring the strength of the slabs and
providing a clean feeling of touch to the homeowners and other end
final users.
Technology has recently improved the quality of these systems,
ensuring a better natural product at a marginal cost in the final
outcome. And as a result, some of the world's most beautiful
granites are available on a larger scale and at a reduced cost,
allowing the stone industry to deal with quality products virtually
free of defect.
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